Well certainly. Tech would need to start the process of getting the ACC to quit the NCAA. If you don't think that'd matter...
It's funny, 25 years ago, I was told (by a Iowa fan) that the midwestern teams really only care about winning the Big Ten and getting to the Rose Bowl. I thought that was b.s. at the time. I don't anymore. Play in the ACC and drop the NCAA altogether.
The NCAA model is incredibly flawed and really we don't need to be a part of it. Few rules help Tech, which I believe is truly trying to play fair.
It's one thing to think the 4 superconferences will leave the NCAA, but it's another to think they will find a "fair" way to get along. Why do we support anything SEC. Look at Auburn, LSU, Bama, UGA. They all cheat, they all run off players, they all over recruit. Why are we in bed with them in the first place?
Do I believe it a stretch for Tech to pull it off by itself? Of course, but someone has to stand up and be counted. ohio state, uscw, auburn, bama, uga, miami, unc......$24.00.